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B Stabilized phosphorescence spectra from monomer MDP and MND in two-methyltetrahydrofuran (1 × 10−5 M) from the 77 K (top), and polymer PDA and you will PNA regarding the space-temperature (RT) (bottom) happier from the 280 and you can 360 nm. C Polymer motion picture excitation–phosphorescence mapping away from PDA (top) and you may PNA (bottom) at the place-temperature. E Sheer changeover orbitals to the lower triplet alter from MDP and you can MND regarding the gaseous state. It is extremely worth of listing your own homochiral Roentgen-BINAP and you will S-BINAP shown understated differences in the newest spectral molds of just one’s circularly polarized luminescence (CPL) signals shown in to the Additional Fig. Also, however they delivered various other phosphorescent is targeted on the new polymer chain so you can prepare RTP tool with tunable phosphorescence emission of bluish to reddish-colored .
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